The poly(vinylidenefluoride-trifluoroethylene)/Ag composite films are derived by spin-coating and annealed at hydrogen atmosphere. Ag(111) phase labeled at the diffraction peak 2θ=38.1 is observed from X-ray diffraction (XRD) pattern, and it was also proved from scanning electron microscope (SEM) images. A blue shift was observed in the infrared transmission spectrum of the composite films, which suggests the interaction of dipole and silver nanoparticles. The ferroelectric polarization and dielectric constant of P(VDF-TrFE)/Ag composite thin films increase by 32.5% and 13.3%, respectively, compared with the pure polymer films under air annealing. The dielectric loss tangent of the P(VDF-TrFE)/Ag composite films is independent of Ag doping ratios, which violates the percolation theory.