MoTe2量子点薄膜的制备及椭圆偏振光谱研究
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1.云南师范大学 能源与环境科学学院 可再生能源材料先进技术与制备教育部重点实验室,云南 昆明 650500;2.昆明物理研究所,云南 昆明 650223;3.云南省先进光电材料与器件重点实验室,云南 昆明650223

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中图分类号:

O433.4

基金项目:

国家重点研发计划 (2019YFB2203404); 云南省科技厅科技人才与平台计划项目 (202205AC160026)


Study on the preparation and spectroscopic ellipsometry of MoTe2 quantum dot films
Author:
Affiliation:

1.Key Laboratory of Advanced Technique& Preparation for Renewable Energy Materials, Ministry of Education, School of Energy and Environment Science, Yunnan Normal University, Kunming 650500, China;2.Kunming Institute of Physics, Kunming 650223, China;3.Yunnan Key Laboratory of Advanced Photoelectric Materials & Devices, Kunming 650223, China

Fund Project:

Supported by the National Key Research and Development Program(2019YFB2203404), Science and Technology Talents and Platform Project of Science and Technology Department of Yunnan Province (202205AC160026)

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    摘要:

    量子点薄膜的制备和光学常数的准确测定对量子点在光电领域的发展应用非常重要。目前通过机械剥离和化学气相沉积制备的MoTe2单晶薄膜的光学常数测定较为成熟,然而,MoTe2量子点薄膜的光学常数的报道却较为少见。采用超声辅助液相剥离的方法制备出MoTe2量子点,并通过改变辅助溶剂的种类与超声顺序制备了两种尺寸的MoTe2量子点;使用椭圆偏振光谱技术,通过B-spline模型和Tauc-Lorentz模型分别研究了两种尺寸量子点薄膜的折射率、消光系数与介电常数等光学常数。结果显示,两种尺寸的MoTe2量子点在可见到红外波段内具有相近的折射率、消光系数和较宽的光谱吸收区,并且与MoTe2体材料相比,具有较低的介电常数。

    Abstract:

    The preparation of quantum dot thin films and the accurate measurement of optical constants are particularly important for the development and application of quantum dot devices in optoelectronic fields. At present, the optical constants of MoTe2 single-crystal films prepared by mechanical exfoliation and chemical vapor deposition are relatively mature. However, the optical constants of 2H-MoTe2 quantum dot films are rarely reported.In this work, 2H-MoTe2 quantum dots were prepared by ultrasonic assisted liquid phase exfoliation, and of 2H-MoTe2 quantum dots with two sizes were acquired via adjusting the type of solvent and the order of ultrasonic process. The optical constants such as refractive index, extinction coefficient and dielectric constant of quantum dot films of two sizes were studied by B-spline model and Tauc-Lorentz model using ellipsometry. The results demonstrate that the 2H-MoTe2 quantum dots with two sizes have similar refractive index, extinction coefficient and a wider spectral absorption in the visible to near infrared band. And compared with MoTe2 bulk material, 2H-MoTe, quantom dots have a lower dielectric constant.

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李国彬,胡坤,张泰玮,杨奥,夏溢坪,李学铭,唐利斌,杨培志,王善力,陈晟迪,杨丽,张艳. MoTe2量子点薄膜的制备及椭圆偏振光谱研究[J].红外与毫米波学报,2025,44(2):148~155]. LI Guo-Bin, HU Kun, ZHANG Tai-Wei, YANG Ao, XIA Yi-Ping, LI Xue-Ming, TANG Li-Bin, YANG Pei-Zhi, WANG Shan-Li, CHEN Sheng-Di, YANG Li, ZHANG Yan. Study on the preparation and spectroscopic ellipsometry of MoTe2 quantum dot films[J]. J. Infrared Millim. Waves,2025,44(2):148~155.]

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历史
  • 收稿日期:2024-08-12
  • 最后修改日期:2025-02-18
  • 录用日期:2024-10-17
  • 在线发布日期: 2025-02-08
  • 出版日期: 2025-04-25
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